Additional Information About Method and Parameter Approvals
This page lists letters and memorandums of approval for methods by various authorities including the Director of the Division of Water Quality, EPA and the Division of Waste Management UST and Solid Waste Sections.
A Note About Individual Organic Analyte Certification
We often receive requests for certification for individual organic analytes. The NC WW/GW LC program is a method certification program and we do not certify for individual organic analytes. If the laboratory holds certification for a method in which the analyte is published within the scope of that method, the laboratory is considered to be certified for analysis of that analyte. In the case where the analyte of interest is not within the scope of a published certifiable method (an example of this would be Tetrahydrofuran by SW-846 Method 8260 B), the laboratory is advised to maintain Method Detection Limit (MDL) and Initial Demonstration of Capability (IDOC) study summary data on file at the laboratory and follow the quality control requirements outlined in the reference method. Any questions (such as whether an analyte of interest may be reported as a Tentatively Identified Compound [TIC] or whether is must be quantitated) should be directed to the regulatory agency receiving the data. This office does not have the authority to certify or otherwise offer any approval for analysis of individual analytes not within the scope of a certifiable method.
Ferrous Iron
The NC WW/GW LC program does not have the authority to certify specifically for the Ferrous state of Iron. We do certify for Total Iron by a method that also allows for measurement of the ferrous state (i.e., Standard Methods 3500-Fe B, 20th Edition and beyond). To measure the ferrous state, however, samples must be analyzed at the sampling site. The program will only certify:
- entities which intend to report Total Iron by this method, or
- entities which intend to report Ferrous Iron by this method and have the capability to analyze samples at the sampling location
Data analyzed, reported and qualified as out of hold time is unusable for the regulatory data receivers' objectives.
For Approved Procedures for the Analysis of Field Parameters
Click here to link to the approved procedures for Total Residual Chlorine, pH, Dissolved Oxygen, Specific Conductance, Termperature and Settleable Residue.
DWQ Director Approval Letters for Additional Certifiable Parameters
| Approval to certify for Acidity, Ignitability, Paint Filter Liquids, Boron, Potassium, Sodium and Total Organic Halides (TOX) | 10/28/2002 |
| Approval to certify for Strontium, Titanium, Lithium, Silica, CBOD, DOC, VSS, E. coli and Enterococci | 03/02/2007 |
| Approval to certify for Volatile Solids and Salinity | 10/05/2007 |
| Letter removing approval of Chlorophyll a by HPLC | 10/11/2007 |
| Approval to certify for Free Available Chlorine | 09/27/2012 |
| Approval to certify for Bromide | 10/11/2012 |
| Approval to certify for Clostridium perfringens and Coliphage | |
DWQ Point Source Branch Letters
| Total Residual Chlorine instrument sensitivity must detect below NPDES discharge permit requirements | 08/14/2001 |
| Total Residual Chlorine Compliance Limit is 50 µg/L | 05/01/2008 |
EPA Approval Letters
| US EPA Letter of approval for additional Metals not included in 40 CFR Part 136.3, Table IB - Methods 200.7 and 200.8 | 11/07/2007 |
| US EPA approval letter to Regional Administrators for use of Luminescence Dissolved Oxygen (LDO) technology for DO and BOD analysis of wastewater - ASTM D888-05 | 01/03/2006 |
| US EPA Region 4 approval letter for use of LDO technology for DO and BOD analysis of wastewater - ASTM D888-05 | 06/01/2006 |
| US EPA approval letter for use of Luminescence Dissolved Oxygen (LDO) technology for DO and BOD analysis of wastewater - Hach 10360 | 07/26/2006 |
| US EPA Region 4 approval letter for use of LDO technology for DO and BOD analysis of wastewater - Hach 10360 | 07/01/2007 |
| US EPA letter regarding allowable modifications to EPA Method 1664 A - HEM: Oil and Grease | 01/16/2009 |
| US EPA letters regarding ATP review of Colilert®-18 for Fecal Coliform analysis | 07/28/2010 |
| US EPA Region 4 Colilert®-18 ATP approval requirements for the Detection and Enumeration of Fecal Coliforms in Wastewater Samples (Instructions for obtaining certification for fecal coliform by Colilert-18® can be found here.) coming soon | 10/01/2010 |
| US EPA Letter regarding ATP approval of NCASI Method 71.01, "An Update of Procedures for the Measurement of Color in Pulp Mill Wastewaters", May 2000 | 11/08/2001 |
| US EPA Letter regarding ATP approval of Hach Company Method 10206 - Spectrophotometric Measurement of Nitrate in Water and Wastewater | 01/31/2013 |
| US EPA Letter regarding ATP approval of Hach Company Method 10242 - Simplified Spectrophotometric Measurement of Total Kjeldahl Nitrogen in Water and Wastewater | 01/31/2013 |
Division of Waste Management - UST and Solid Waste Section Guidelines
| Link to UST Update on the January, 1998 MADEP Method, effective 02/01/2006, to the May, 2004 Revision 1.1 | 12/07/2005 |
| UST Section request to certify commercial laboratories for EPA SW-846 method 8015B for Total Petroleum Hydrocarbons | 03/26/2003 |
| Memorandum regarding changes in UST guidelines | 11/25/2008 |
| Guidelines for Site Check, Tank Closure and Initial Response and Abatement for UST Releases - revision 1 | 11/26/2008 |
| Guidelines for Assessment and Corrective Action for UST Releases | 11/26/2008 |
| Guidelines for Sampling - UST [Summary of Appendix B changes 05/01/2012] | 05/01/2012 |
| Solid Waste Section Memorandum regarding THF monitoring at Construction and Demolition Landfills | 06/25/2010 |
Aquifer Protection Section
| APS Policy for Metals determination required by 15A NCAC 2L - SM 3030C is no longer required. | 04/13/2013 |
Additional Links
Information on the Methods Update Rule (MUR)
Information on the use of Discrete Analyzers
Information on SW-846 Updates IVA and IVB
Information on Horizon EPA Method 1664 A Compliance Options